Using ScreenCapture.CaptureScreenshot freezes Unity Editor (2019.4.26f1)

I've been working in a project some weeks now in a Mixed Reality project using Unity and MRTK and I've found a strange behaviour when adding screen capture to the application. I'm using Unity 2019.4.26f1, and I haven't found any issues so far but after adding this line of code

 ScreenCapture.CaptureScreenshot("test.png");

into a script, I've realised that when I press Play and go into Game mode, everything goes correctly (the game starts, the screenshot is taken). BUT when I stop it and try to go into Play mode again, Unity freezes. If I don't press Play again, Unity still works until it tries to compile scripts or some heavy task like that, when it freezes and can only be closed with the task manager.

If I remove that line, Unity goes back to normal.