Couldn't resolve host name url: https://kharma.unity3d.com/

I am currently not on a wireless connection that has any sort of web blockers other than an ad blocker. I use google chrome. I got through Century Link ISP. I have ample space on my hard drive. I am signed in. I am on the latest version of unity as of October 24th 2013. My Asset Store will not load due to it saying i am in offline mode. Please help. I've tried the previous threads about fixes by changing my environmental settings in my comp settings to no avail. Please help.